Wednesday, February 27, 2013

Redox & Electrochemistry

Oxidation: loss of electrons
Reduction: gain of electrons

Oxidizing Agent: substance reduced
Reducing Agent: substance oxidized

Anode: electrode where oxidation occurs (AN OX)
Cathode: electrode where reduction occurs (RED CAT)

Salt Bridge: allows the flow of ions between the anode and cathode solutions to keep a balance of charge
  • Cations flow toward the Cathode
  • Anions flow toward the Anode

Single replacement reactions are always Redox – Table J is used to predict  which metal will replace another. More active free metal will replace less active metal in a compound.
Double replacements never are Redox. 

Electrochemical Cells (Voltaic Cells)
  • Batteries
  • Spontaneous redox reaction
  • Generates Electric Current
  • Positive Voltage
  • Anode is NEGATIVE
  • Cathode is POSITIVE
  • Cathode gains weight
  • Electrons move from Anode --> Cathode


Electrolytic Cells
  • Non-spontaneous redox reaction
  • Electricity must be used for reaction to occur
  • Negative Voltage
  • Used to obtain pure elements from aqueous ions
  • Anode is POSITIVE
  • Cathode is NEGATIVE
  • Electrons move from Cathode --> Anode